Araştırma Makalesi
BibTex RIS Kaynak Göster

Yeni Tür Yeşil Korozyon İnhibitörü Olarak Citrus aurantium Meyve Kabukları Ekstraktının HCl Çözeltisindeki Yumuşak Çelik Korozyonu Üzerine Kararlı Etkisi

Yıl 2022, Cilt: 5 Sayı: 2, 165 - 172, 31.12.2022

Demet Özkır

https://doi.org/10.55117/bufbd.1117000

Öz

Citrus aurantium meyve kabuğu özütü çözeltisinin mevcut araştırmadaki rolü, çevre dostu ve yeşil etkisi ile atmosfer ortamında, yumuşak çelik üzerinde korozyon inhibitörü olarak etkisini araştırmaktır. Citrus aurantium’un inhibitör etkisi, lineer polarizasyon (LPR), potansiyodinamik polarizasyon ve elektrokimyasal impedans spektroskopisi (EIS) yöntemleri kullanılarak çalışılmıştır. Her ölçümden bir saat önce, çalışma elektrotları metal-çözelti arayüzeyini dengelemek amacıyla farklı derişimlerdeki Citrus aurantium meyve kabukları özütünü içeren HCl çözeltilerine daldırılmıştır. Turunç meyvesi kabuklarının özütü bir saatlik elektrokimyasal testler sonucunda potansiyel bir inhibitör etki göstermiş ve Citrus aurantium meyve kabuklarının özüt derişimlerinin artmasıyla, HCl çözeltilerindeki yumuşak çelik elektrotları koruma etkisi de artmıştır. Son olarak, bir saatlik daldırma işlemi sonrasında turunç meyvesi kabuğu ekstraktını içeren ve içermeyen 1,0 M HCl çözeltilerindeki çalışma elektrotlarının yüzey morfolojileri, optik mikroskopla incelenmiş ve inhibitör ekstrakt çözeltisindeki yumuşak çeliğin yüzeyinin inhibitör içermeyen yüzeye kıyasla daha pürüzsüz olduğu sonucuna varılmıştır. Deneysel veriler ve yüzey morfoloji sonuçları birbirleriyle son derece uyumludur.

Anahtar Kelimeler

Citrus aurantium EIS Yeşil inhibitör Asidik korozyon Optik mikroskop

Kaynakça

  • [1] M. Şahin, E. Çadırlı, Y. Sürme, and D. Özkır, “Thermo-Electrical Properties in Pb-Sb Hypereutectic Alloy,” Met. Mater. Int., vol. 19, no. 3, pp. 465-472, 2013.
  • [2] C. A. Loto, and R. T. Loto, “Effects of Lavandula and Ricinus Ϲommunis Oil as Inhibitors of Mild Steel Ϲorrosion in HCl and H2SO4 Media,” Procedia Manuf., vol. 35, pp. 407-412, 2019.
  • [3] D. Özkır, “The role of Lavandula sp. extract for effective inhibiting the mild steel corrosion in the hydrochloric acid solution,” Int. J. Chem. Technol., vol. 5, no. 2, pp. 125-132, 2021.
  • [4] P. E. Alvarez, M. V. Fiori-Bimbi, A. Neske, S. A. Brandán, and C. A. Gervasi, “Rollinia occidentalis extract as green corrosion inhibitor for carbon steel in HCl solution,” J. Ind. Eng. Chem., vol. 58, pp. 92-99, 2018.
  • [5] Y. Zhang, Q. Xu, M. Sun, C. Xiong, P. Wang, Z. Chen, G. Sun, J. Guan, Z. Ding, M. Li, and D. Hou, “Insights into vitamin B3, B6 and C as inhibitor of steel reinforcement: A DFT + U study,” Constr. Build. Mater., vol. 294, pp. 123571, 2021.
  • [6] A. Dehghani, G. Bahlakeh, and B. Ramezanzadeh, “A detailed electrochemical/theoretical exploration of the aqueous Chinese gooseberry fruit shell extract as a green and cheap corrosion inhibitor for mild steel in acidic solution,” J. Mol. Liq., vol. 282, pp. 366–384, 2019.
  • [7] E. S. Ferreira, C. Giacomelli, F. C. Giacomelli, and A. Spinelli, “Evaluation of the inhibitor effect of Lascorbic acid on the corrosion of mild steel,” Mater. Chem. Phys., vol. 83, pp. 129–134, 2004.
  • [8] S. Pasandideh, and A. Arasteh, “Evaluation of antioxidant and inhibitory properties of Citrus aurantium L. on the acetylcholinesterase activity and the production of amyloid nano–bio fibrils,” Int. J. Biol. Macromol., vol. 182, pp. 366-372, 2021.
  • [9] S. Ringwal, A. S. Bartwal, and S. C. Sati, “Photo-catalytic degradation of different toxic dyes using silver nanoparticles as photo-catalyst, mediated via Citrus aurantium peels extract,” J. Indian Chem. Soc., vol. 98, pp. 100221, 2021.
  • [10] K. Wolfe, X. Wu, and R. H. Liu, “Antioxidant Activity of Apple Peels,” J. Agric. Food Chem., vol. 51, pp. 609-614, 2003.
  • [11] J. K. Moon, and T. Shibamoto, “Antioxidant assays for plant and food components,” J. Agric. Food Chem., vol. 57, no. 5, pp. 1655–1666, 2009.
  • [12] J. R. Scully, D. C. Silverman, and M. W. Kending, eds., Electrochemical impedance: Analysis and interpretation. ASTM publication code number (PCN): 04-011880-27, Printed in Fredericksburg, VA, TA418.74.E43, pp. 1-480, 1993. Accessed on: Apr. 05, 2022, [Online] Available: https://www.astm.org/stp1188-eb.html
  • [13] D. Özkır, “A Newly Synthesized Schiff Base Derived from Condensation Reaction of 2,5-dichloroaniline and benzaldehyde: Its Applicability through Molecular Interaction on Mild Steel as an Acidic Corrosion Inhibitor by Using Electrochemical Techniques,” J. Electrochem. Sci. Technol., vol. 10, no. 1, pp. 37–54, 2019.
  • [14] H. Kahkesh, and B. Zargar, “Corrosion protection evaluation of Allium Jesdianum as a novel and green source inhibitor for mild steel in 1M HCl solution,” J. Mol. Liq., vol. 344, pp. 117768, 2021.
  • [15] D. Özkır, “An Overview of Plagiochila porelloides (Marchantiophyta) as a New Environmentally Sustainable Green Corrosion Inhibitor for Mild Steel in Acidic Solution,” Anatolian Bryol., vol. 7, no. 2, pp. 119-130, 2021.
  • [16] N. V. Likhanova, P. Arellanes-Lozada, O. Olivares-Xometl, H. Hernández-Cocoletzi, I. V. Lijanova, J. Arriola-Morales, and J. E. Castellanos-Aguila, “Effect of organic anions on ionic liquids as corrosion inhibitors of steel in sulfuric acid solution,” J. Mol. Liq., vol. 279, pp. 267–278, 2019.
  • [17] D. Özkır, and K. Kayakırılmaz, “The Inhibitor Effect of (E)-5-[(4-(benzyl(methyl)amino)phenyl)diazenyl]- 1,4-dimethyl-1H-1,2,4-triazol-4-ium zinc(II) Chloride, an Industrial Cationic Azo Dye, onto Reducing Acidic Corrosion Rate of Mild Steel,” J. Electrochem. Sci. Technol., vol. 11, no. 3, pp. 257-272, 2020.
  • [18] B. S. Prathibha, H. P. Nagaswarupa, P. Kotteeswaran, V. BheemaRaju, “Inhibiting effect of Quaternary ammonium compound on the corrosion of mild steel in 1M Hydrochloric acid solution, its adsorption and kinetic characteristics,” Mater. Today., pp. 12245–12254, 2017.
  • [19] V. N. Statsyuk, S. Ait, L. A. Fogel, M. Z. Zhurinov, and A. A. Abrashov, “Corrosion Effect on Iron Electrode in Presence of Heterocyclic Amines,” Orient. J. Chem., vol. 33, pp. 2868-2874, 2017.
  • [20] N. D. Nam, P. V. Hien, N. T. Hoai, and V. T. H. Thu, “A study on the mixed corrosion inhibitor with a dominant cathodic inhibitor for mild steel in aqueous chloride solution,” J. Taiwan Inst. Chem. Eng., vol. 91, pp. 556-569, 2018.
  • [21] E. d. B. Policarpi, and A. Spinelli, “Application of Hymenaea stigonocarpa fruit shell extract as eco-friendly corrosion inhibitor for steel in sulfuric acid,” J. Taiwan Inst. Chem. Eng., vol. 116, pp. 215-222, 2020.

The Consistent Effect of Citrus aurantium Fruit Peels Extract as New Type Green Inhibitor on Mild Steel Corrosion in HCl Solution

Yıl 2022, Cilt: 5 Sayı: 2, 165 - 172, 31.12.2022

Demet Özkır

https://doi.org/10.55117/bufbd.1117000

Öz

The role of Citrus aurantium fruit peel extract solution in the existing research is to investigate the effect as corrosion inhibitor on mild steel in the atmospheric environment with its eco-friendly and green effect. It was studied the inhibitor effect of Citrus aurantium utilizing linear polarization (LPR), potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) methods. The working electrodes were immersed in HCl solutions containing various concentrations of Citrus aurantium fruit peels extract in order to equilibrate the metal-solution interface for one hour before each measurement. The bitter orange fruit peels extract indicated a potent inhibitor influence as a consequence of one hour electrochemical tests, and with the raise of extract concentrations of Citrus aurantium fruit peels, the protection influence of mild steel electrodes in HCl solutions also enhanced. Finally, the surface morphologies of the working electrodes in aggressive HCl solutions without and with bitter orange fruit peels extract after one-hour immersion were analysed by an optical microscopy, it was concluded that the mild steel surface in the Citrus aurantium fruit peels extract solution had a flawless surface compared to the blank one. Experimental data and surface morphology results are highly consistent with each other.

Anahtar Kelimeler

Citrus aurantium EIS Green inhibitor Acidic corrosion Optical microscope

Kaynakça

  • [1] M. Şahin, E. Çadırlı, Y. Sürme, and D. Özkır, “Thermo-Electrical Properties in Pb-Sb Hypereutectic Alloy,” Met. Mater. Int., vol. 19, no. 3, pp. 465-472, 2013.
  • [2] C. A. Loto, and R. T. Loto, “Effects of Lavandula and Ricinus Ϲommunis Oil as Inhibitors of Mild Steel Ϲorrosion in HCl and H2SO4 Media,” Procedia Manuf., vol. 35, pp. 407-412, 2019.
  • [3] D. Özkır, “The role of Lavandula sp. extract for effective inhibiting the mild steel corrosion in the hydrochloric acid solution,” Int. J. Chem. Technol., vol. 5, no. 2, pp. 125-132, 2021.
  • [4] P. E. Alvarez, M. V. Fiori-Bimbi, A. Neske, S. A. Brandán, and C. A. Gervasi, “Rollinia occidentalis extract as green corrosion inhibitor for carbon steel in HCl solution,” J. Ind. Eng. Chem., vol. 58, pp. 92-99, 2018.
  • [5] Y. Zhang, Q. Xu, M. Sun, C. Xiong, P. Wang, Z. Chen, G. Sun, J. Guan, Z. Ding, M. Li, and D. Hou, “Insights into vitamin B3, B6 and C as inhibitor of steel reinforcement: A DFT + U study,” Constr. Build. Mater., vol. 294, pp. 123571, 2021.
  • [6] A. Dehghani, G. Bahlakeh, and B. Ramezanzadeh, “A detailed electrochemical/theoretical exploration of the aqueous Chinese gooseberry fruit shell extract as a green and cheap corrosion inhibitor for mild steel in acidic solution,” J. Mol. Liq., vol. 282, pp. 366–384, 2019.
  • [7] E. S. Ferreira, C. Giacomelli, F. C. Giacomelli, and A. Spinelli, “Evaluation of the inhibitor effect of Lascorbic acid on the corrosion of mild steel,” Mater. Chem. Phys., vol. 83, pp. 129–134, 2004.
  • [8] S. Pasandideh, and A. Arasteh, “Evaluation of antioxidant and inhibitory properties of Citrus aurantium L. on the acetylcholinesterase activity and the production of amyloid nano–bio fibrils,” Int. J. Biol. Macromol., vol. 182, pp. 366-372, 2021.
  • [9] S. Ringwal, A. S. Bartwal, and S. C. Sati, “Photo-catalytic degradation of different toxic dyes using silver nanoparticles as photo-catalyst, mediated via Citrus aurantium peels extract,” J. Indian Chem. Soc., vol. 98, pp. 100221, 2021.
  • [10] K. Wolfe, X. Wu, and R. H. Liu, “Antioxidant Activity of Apple Peels,” J. Agric. Food Chem., vol. 51, pp. 609-614, 2003.
  • [11] J. K. Moon, and T. Shibamoto, “Antioxidant assays for plant and food components,” J. Agric. Food Chem., vol. 57, no. 5, pp. 1655–1666, 2009.
  • [12] J. R. Scully, D. C. Silverman, and M. W. Kending, eds., Electrochemical impedance: Analysis and interpretation. ASTM publication code number (PCN): 04-011880-27, Printed in Fredericksburg, VA, TA418.74.E43, pp. 1-480, 1993. Accessed on: Apr. 05, 2022, [Online] Available: https://www.astm.org/stp1188-eb.html
  • [13] D. Özkır, “A Newly Synthesized Schiff Base Derived from Condensation Reaction of 2,5-dichloroaniline and benzaldehyde: Its Applicability through Molecular Interaction on Mild Steel as an Acidic Corrosion Inhibitor by Using Electrochemical Techniques,” J. Electrochem. Sci. Technol., vol. 10, no. 1, pp. 37–54, 2019.
  • [14] H. Kahkesh, and B. Zargar, “Corrosion protection evaluation of Allium Jesdianum as a novel and green source inhibitor for mild steel in 1M HCl solution,” J. Mol. Liq., vol. 344, pp. 117768, 2021.
  • [15] D. Özkır, “An Overview of Plagiochila porelloides (Marchantiophyta) as a New Environmentally Sustainable Green Corrosion Inhibitor for Mild Steel in Acidic Solution,” Anatolian Bryol., vol. 7, no. 2, pp. 119-130, 2021.
  • [16] N. V. Likhanova, P. Arellanes-Lozada, O. Olivares-Xometl, H. Hernández-Cocoletzi, I. V. Lijanova, J. Arriola-Morales, and J. E. Castellanos-Aguila, “Effect of organic anions on ionic liquids as corrosion inhibitors of steel in sulfuric acid solution,” J. Mol. Liq., vol. 279, pp. 267–278, 2019.
  • [17] D. Özkır, and K. Kayakırılmaz, “The Inhibitor Effect of (E)-5-[(4-(benzyl(methyl)amino)phenyl)diazenyl]- 1,4-dimethyl-1H-1,2,4-triazol-4-ium zinc(II) Chloride, an Industrial Cationic Azo Dye, onto Reducing Acidic Corrosion Rate of Mild Steel,” J. Electrochem. Sci. Technol., vol. 11, no. 3, pp. 257-272, 2020.
  • [18] B. S. Prathibha, H. P. Nagaswarupa, P. Kotteeswaran, V. BheemaRaju, “Inhibiting effect of Quaternary ammonium compound on the corrosion of mild steel in 1M Hydrochloric acid solution, its adsorption and kinetic characteristics,” Mater. Today., pp. 12245–12254, 2017.
  • [19] V. N. Statsyuk, S. Ait, L. A. Fogel, M. Z. Zhurinov, and A. A. Abrashov, “Corrosion Effect on Iron Electrode in Presence of Heterocyclic Amines,” Orient. J. Chem., vol. 33, pp. 2868-2874, 2017.
  • [20] N. D. Nam, P. V. Hien, N. T. Hoai, and V. T. H. Thu, “A study on the mixed corrosion inhibitor with a dominant cathodic inhibitor for mild steel in aqueous chloride solution,” J. Taiwan Inst. Chem. Eng., vol. 91, pp. 556-569, 2018.
  • [21] E. d. B. Policarpi, and A. Spinelli, “Application of Hymenaea stigonocarpa fruit shell extract as eco-friendly corrosion inhibitor for steel in sulfuric acid,” J. Taiwan Inst. Chem. Eng., vol. 116, pp. 215-222, 2020.
Toplam 21 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Kimya Mühendisliği
Bölüm Araştırma Makaleleri
Yazarlar

Demet Özkır 0000-0002-8096-5755

Erken Görünüm Tarihi 28 Aralık 2022
Yayımlanma Tarihi 31 Aralık 2022
Yayımlandığı Sayı Yıl 2022 Cilt: 5 Sayı: 2

Kaynak Göster

APA Özkır, D. (2022). The Consistent Effect of Citrus aurantium Fruit Peels Extract as New Type Green Inhibitor on Mild Steel Corrosion in HCl Solution. Bayburt Üniversitesi Fen Bilimleri Dergisi, 5(2), 165-172. https://doi.org/10.55117/bufbd.1117000
AMA Özkır D. The Consistent Effect of Citrus aurantium Fruit Peels Extract as New Type Green Inhibitor on Mild Steel Corrosion in HCl Solution. Bayburt Üniversitesi Fen Bilimleri Dergisi. Aralık 2022;5(2):165-172. doi:10.55117/bufbd.1117000
Chicago Özkır, Demet. “The Consistent Effect of Citrus Aurantium Fruit Peels Extract As New Type Green Inhibitor on Mild Steel Corrosion in HCl Solution”. Bayburt Üniversitesi Fen Bilimleri Dergisi 5, sy. 2 (Aralık 2022): 165-72. https://doi.org/10.55117/bufbd.1117000.
EndNote Özkır D (01 Aralık 2022) The Consistent Effect of Citrus aurantium Fruit Peels Extract as New Type Green Inhibitor on Mild Steel Corrosion in HCl Solution. Bayburt Üniversitesi Fen Bilimleri Dergisi 5 2 165–172.
IEEE D. Özkır, “The Consistent Effect of Citrus aurantium Fruit Peels Extract as New Type Green Inhibitor on Mild Steel Corrosion in HCl Solution”, Bayburt Üniversitesi Fen Bilimleri Dergisi, c. 5, sy. 2, ss. 165–172, 2022, doi: 10.55117/bufbd.1117000.
ISNAD Özkır, Demet. “The Consistent Effect of Citrus Aurantium Fruit Peels Extract As New Type Green Inhibitor on Mild Steel Corrosion in HCl Solution”. Bayburt Üniversitesi Fen Bilimleri Dergisi 5/2 (Aralık 2022), 165-172. https://doi.org/10.55117/bufbd.1117000.
JAMA Özkır D. The Consistent Effect of Citrus aurantium Fruit Peels Extract as New Type Green Inhibitor on Mild Steel Corrosion in HCl Solution. Bayburt Üniversitesi Fen Bilimleri Dergisi. 2022;5:165–172.
MLA Özkır, Demet. “The Consistent Effect of Citrus Aurantium Fruit Peels Extract As New Type Green Inhibitor on Mild Steel Corrosion in HCl Solution”. Bayburt Üniversitesi Fen Bilimleri Dergisi, c. 5, sy. 2, 2022, ss. 165-72, doi:10.55117/bufbd.1117000.
Vancouver Özkır D. The Consistent Effect of Citrus aurantium Fruit Peels Extract as New Type Green Inhibitor on Mild Steel Corrosion in HCl Solution. Bayburt Üniversitesi Fen Bilimleri Dergisi. 2022;5(2):165-72.
 Kapak Resmi İndir

Taranılan Dizinler